A little makes a lot?
| By John Busby | ||
| 7 August 2007
|
||
|
Natural uranium contains only 0.7% of the fissionable isotope U-235 and has to be enriched to around 3.6% to 4.5% for use in a modern reactor. This is a complex process involving the conversion of uranium, a heavy metal, into a gas (uranium hexafluoride) in which form the fissionable component can be increased by centrifuging or by diffusion. The gas is then re-converted into a solid oxide from which the nuclear fuel is manufactured. The enrichment process produces "tails" with a lowered U–235 content of 0.2% to 0.3% from the original 0.7%. The tails remain as a gas and are stored in cylinders, awaiting disposal or re-processing. Starting with 207 tonnes of natural uranium the process produces 30 tonnes of uranium dioxide (containing 25 tonnes of uranium of both kinds) from which sufficient fuel is manufactured to run a one GW (a gigawatt = thousand megawatts or a million kilowatts) nuclear power station for a year. The UK uranium requirement for 2007 amounts to 2158 tonnes of natural uranium equivalent, which at the current price of uranium of US $338/kg (US $130/lb U3O8) is valued at US $730 million, though probably acquired for less under current supply contracts. Thus 2,000 tonnes of natural uranium fuels just over 9 GW of electricity generation or 79 TWh (terawatthours).
In comparison, a 1 GW coal-fired station consumes 2.87 million tonnes of coal per annum, which together with the removal of its overburden of say ½ million tonnes would mean the removal of a similar amount of material to that shifted and milled for an equivalent nuclear power station reliant on the lower ore grades. Apart from some sorting and washing, the coal extracted is used more or less as it is, but uranium ore has to be milled and chemically treated to produce triuranium octoxide (U3O8) known as "yellow cake", although it is green, in which form it is drummed off for export. So a little uranium comes from a lot of stuff. How much is the lot of the "little"?Global natural uranium consumption in 2006 amounted to around an equivalent 65,000 tonnes, of which just under 40,000 tonnes of primary production came from mines. The missing 25,000 tonnes came from diluted ex-weapons highly-enriched uranium (HEU) from Russia, from inventories, from re-worked mine tailings and from a small amount of mixed-oxide fuel (MOX) made from recovered plutonium and depleted uranium.
Under a US-Russian HEU purchase agreement, 500 tonnes of HEU from over 30,000 dismantled Russian nuclear weapons is being blended with low enriched uranium (LEU) by 2013. [1] Under the agreement, around 30 tonnes of HEU is processed annually in Russia to produce the equivalent of around half of the US natural uranium demand of 20,000 tonnes. It is necessary to understand "equivalent" because the fuel is supplied to the US as uranium hexafluoride gas (UF6) in cylinders at the correct level of enrichment (i.e. 4% - 4.5% U-235) in an amount which would arise from a feed of 10,000 tonnes of natural uranium to a normal nuclear fuel manufacturing process. The Russians enrich UF6 tails (of 0.2% to 0.3% U-235 content) from their conventional enrichment processes (up to 1.5% U-235 content) for blending with the HEU (of 90% U-235 content) (which has first been extracted from dismantled weapons) and converted to UF6 gas so that the two streams of gas can be mixed. This is a very good deal for the US as it means that half of its enrichment needs are provided in Russia, which is left with the disposal problem of the enrichment tails. As Russian natural uranium production is in deficit (3,400 tonnes cf. 3800 tonnes demand) and there are plans to build more nuclear stations, it is unlikely that the agreement will be continued after 2013. A new enrichment plant is under construction in the US, but this will require the procurement of an additional 10,000 tonnes of natural uranium to replace the Russian HEU/LEU blended supplies, as well as providing for the enrichment of the other 10,000 tonnes of the 20,000 tonnes the US uses for its nuclear generation. The other 15,000 tonnes per annum from the so-called secondary supplies comprising inventories and re-worked tailings is also expected to end with the ex-weapons material by 2013, with the exception of a little MOX production in France and Japan. What happens when the secondary supplies are gone?Meanwhile primary mining production fell 5% in 2006 over that in 2005. The biggest producers, Canada and Australia saw falls of 15% and 20%, with only Kazakhstan showing an increase. [2]
There are only two mines of adequate size likely to fill part of the gap in the available time scale, Cigar Lake in Canada in 2011 if it overcomes its flooding problems and Olympic Dam in Australia in 2014 if it passes its current feasibility study in 2009. [3] The anticipated production is 7,000 tonnes and 15,000 tonnes per annum respectively, but together they have no chance of filling a gap of between 25,000 tonnes to 48,000 tonnes, depending on the prevailing circumstances. Both projects are characterised with serious deficiencies. Cigar Lake needs four years of refrigeration to contain the water in the sandstone above the workings, consuming 10 gigawatthours of electricity meantime before mining can begin, while Olympic Dam as an open pit is initiated by four years of excavation of 3 cubic kilometres of rock before the first kilogram of uranium is reached requiring 5 to 6 million tonnes of imported diesel. Although Cigar Lake produces a lot of water from the flooding it is contaminated, but could presumably supply its own process water. In contrast, the Olympic Dam copper and uranium processing requires water, but it is situated in an area subject to severe drought and will require the building of a desalination plant. So a "little" uranium needs a lot of diesel, electricity and water or refrigeration to cope with too much water. Can a little be done with a lot of enrichment "tails"?
As uranium becomes less available, proportionally more fuel can be produced by employing more enrichment facilities. There are limits as to how much can be economically gained, but the U-235 content in the "tails" would be reduced, producing more in the "heads". '[4] To make use of the increasing inventory of enrichment tails, a massive investment in gas centrifuges would need to be made. For example in the UK around 25,000 tonnes of uranium resides in enrichment tails. To recover enough of the U-235 content to produce 2,000 tonnes of fuel by reducing the tails content from 0.3% to 0.1% would require 23 million SWU's, compared with around 1.2 million SWU's currently employed to fuel the existing fleet of reactors. Can a little be done with the accumulated spent fuel? |
||